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    • 专利摘要:
    The invention relates to a method for deep conversion of a heavy hydrocarbon feedstock comprising the following steps: a) a first step of hydroconversion into a bubbling bed of the feedstock, b) a step of separation of at least a part of the feedstock. hydroconverted liquid effluent from step a), c) i) a step of hydrotreating at least a portion of the gas oil fraction and the vacuum gas oil fraction from step b), ii) a first hydrocracking step of at least a portion of the gas oil fraction and of the vacuum gas oil fraction resulting from step b), d) a step of fractionation of at least a portion of the effluent resulting from the step c) i) or step c) ii), e) a step of recycling at least a portion of the unconverted vacuum gas oil fraction from step d) fractionation in said first step a) of hydroconversion, f) a second step of hydrocracking at least a portion of the gas oil fraction resulting from step d) of fract ionisation, g) a step of recycling all or part of the effluent from step f) in fractionation step d).
    公开号:FR3030567A1
    申请号:FR1462713
    申请日:2014-12-18
    公开日:2016-06-24
    发明作者:Frederic Morel；Jacinthe Frecon
    申请人:Axens SA；
    IPC主号:
    专利说明:

    [0001] The invention relates to the field of gasoline production (also often called naphtha) from petroleum residues. The sequence of conversion and hydrocracking units in the treatment of petroleum residue feedstocks is known from the state of the art.
    [0002] US Pat. Nos. 5,980,730 and 6,017,441 disclose a process for deep conversion of a heavy petroleum fraction, said process comprising a three-phase bubbling bed hydroconversion stage, atmospheric distillation of the effluent obtained, vacuum distillation of the atmospheric residue obtained. after this distillation, a deasphalting of the vacuum residue obtained and a hydrotreatment of the deasphalted fraction mixed with the distillate obtained during the distillation under vacuum. It is also possible in this process to send at least a fraction of the hydrotreated effluent to a catalytic cracking section, or to recycle a fraction of the effluent from deasphalting or according to another variant a fraction of the asphalt to the first hydroconversion step or to send a heavy liquid fraction resulting from the hydrotreatment step in a fluidized catalytic cracking section US Pat. No. 6,620,311 describes a conversion process making it possible to increase the yield of middle distillates . This process comprises a step of three-phase bubbling bed conversion, sending the effluent obtained in a separation section to produce a distillate head comprising gas, gasoline and gas oil and basically hydrocarbons having a boiling point higher than an atmospheric gas oil. The distillate is then treated in a hydrodesulfurization unit and the bottom fraction treated in a catalytic cracking section in the absence of hydrogen, for example of the fluidized bed cracking type.
    [0003] This type of cracking thus differs from a hydrocracking operated in fixed bed and in the presence of hydrogen. US Pat. No. 7,919,054 describes a heavy petroleum feedstock treatment plant comprising a bubbling bed hydroconversion section, a separation and a hydrotreatment section in a fixed bed and in the presence of hydrogen of the distillate obtained. This hydrotreatment can be a mild hydrocracking (4.5 to 16 MPa) or a more severe hydrocracking (7 to 20 M Pa). The processes proposed in the prior art, however, suffer from a limitation in the production efficiency of gasoline. In fact, these processes produce a relatively large amount of purge of vacuum distillates at the bottom of the column of the vacuum separation units of the hydroconversion effluents. However, these fractions resulting from vacuum separations, because of their poly-condensed structures, are difficult to recover as an oil base, this in comparison with vacuum distillate fractions from direct distillation of petroleum fractions.
    [0004] The Applicant proposes a new process having a particular arrangement of conversion units and possibly solvent deasphalting to obtain production yields of gasoline (also called naphtha) greater than the processes of the prior art. An object of the invention is to achieve a deep conversion of the oil residue load while maximizing the production of gasoline. The present invention relates to a process for deep conversion of a heavy hydrocarbon feedstock comprising the following steps: a) a first hydroconversion stage in a bubbling bed of the feedstock, in the presence of hydrogen, comprising at least one three-phase reactor containing at least one ebullated bed hydroconversion catalyst; b) a step of separating at least a portion of the hydroconverted liquid effluent from step a) into a gasoline fraction, a gas oil fraction, a fraction vacuum gas oil, and a residual fraction unconverted, C) i) is a step of hydrotreating at least a portion of the gas oil fraction and the vacuum gas oil fraction from step b) in a reactor comprising at least one fixed bed hydrotreatment catalyst, ii) a first hydrocracking step of at least a portion of the gas oil fraction and of the vacuum gas oil fraction resulting from step b) in a reactor comprising at least one fixed-bed hydrocracking catalyst; d) a step of fractionating at least a portion of the effluent from step c) i) or step c) ii) into a gasoline fraction; , a gas oil fraction and an unconverted vacuum gas oil fraction, e) a step of recycling at least a portion of the unconverted vacuum gas oil fraction resulting from the fractionation step d) in said first hydroconversion stage a) f) a second step of hydrocracking at least a portion of the gas oil fraction resulting from fractionation step d); g) a step of recycling all or part of the effluent resulting from step f) in step d) fractionation. The filler according to the present invention is advantageously chosen from heavy hydrocarbon feeds of the atmospheric or vacuum residue type obtained for example by direct distillation of petroleum fraction or by vacuum distillation of crude oil, distillate-type feedstocks such as diesel fuel. vacuum or deasphalted oils, asphalts from solvent deasphalting petroleum residues, coal suspended in a hydrocarbon fraction such as for example gas oil obtained by vacuum distillation of crude oil (also called vacuum gas oil distillation) or so distillate from liquefaction of coal, alone or in mixture. The filler according to the invention may contain vacuum residues such as Arabian Heavy vacuum residues, Ural vacuum residues and the like, vacuum residues from heavy Canadian or Venezuelan type heavy crudes, or a mixture of atmospheric residues. or under vacuum of various origins. DETAILED DESCRIPTION OF THE INVENTION The method according to the invention comprises at least a first hydroconversion step bubbling bed of the load according to the invention. This technology is marketed in particular as the H-Oil IO process. First hydroconversion stage The conditions of the first hydroconversion stage of the feedstock in the presence of hydrogen are usually conventional bubbling bed hydroconversion conditions of a liquid hydrocarbon fraction or coal suspended in a liquid hydrocarbon fraction. The hydroconversion stage a) can be carried out under an absolute pressure of between 5 and 35 MPa, at a temperature of 260 to 600 ° C. and at a liquid hourly space velocity (VVH) of the liquid ranging from 0.05 h -1. at 10 am
    [0005] It is usually carried out under an absolute pressure generally between 5 and 35 MPa, preferably between 10 and 25 MPa, at a temperature of 260 to 600 ° C and often 350 to 550 ° C. The hourly space velocity (VVH) and the hydrogen partial pressure are important factors that are chosen according to the characteristics of the charge to be treated and the desired conversion. Most often the VVH is in a range from 0.05h-1 to 10 h-1 and preferably 0.1 h-1 to 5 h-1. According to the invention, the weighted average temperature of the catalytic bed of the first hydroconversion stage is advantageously between 260 ° C. and 600 ° C., preferably between 300 ° C. and 600 ° C., more preferably between 25 ° C. and 600 ° C. 350 ° C and 550 ° C.
    [0006] The amount of hydrogen mixed with the feed is usually 300 to 2000 normal cubic meters (Nm3) per cubic meter (m3) of liquid feed. Advantageously, the hydrogen is used in a volume ratio with the load of between 500 and 1800 m 3 / m 3, preferably between 600 and 1500 m 3 / m 3. It is possible to use a granular hydroconversion catalyst of residues in bubbling beds comprising on an amorphous support at least one metal compound having a hydrodehydrogenating function. This catalyst may be a catalyst comprising Group VIII metals, for example nickel and / or cobalt, most often in combination with at least one Group VIB metal, for example molybdenum and / or tungsten. For example, a catalyst comprising from 0.5 to 10% by weight of nickel and preferably from 1 to 5% by weight of nickel (expressed as nickel oxide NiO) and from 1 to 30% by weight of molybdenum of preferably from 5 to 20% by weight of molybdenum (expressed as molybdenum oxide MoO 3) on an amorphous mineral support. This support is for example chosen from the group formed by alumina, silica, silica-aluminas, magnesia, clays and mixtures of at least two of these minerals. This support may also contain other compounds and for example oxides chosen from the group formed by boron oxide, zirconia, titanium oxide and phosphoric anhydride. Most often an alumina support is used and very often a support of alumina doped with phosphorus and possibly boron. The concentration of phosphoric anhydride P2O5 is usually less than 20% by weight and most often less than 10% by weight. This P205 concentration is usually at least 0.001% by weight. The concentration of boron trioxide B 2 O 3 is usually from 0 to 10% by weight. The alumina used is usually a gamma or rho alumina. This catalyst is most often in the form of extruded. In all cases, the attrition resistance of the catalyst must be high given the specific constraints of the bubbling beds. The total content of Group VI and VIII metal oxides is often from 5 to 40% by weight and generally from 7 to 30% by weight and the weight ratio of metal oxide (or metals) of group VI metal (or metals) and group VIII (Group VIII oxide / Group VI oxide by weight) is in general from 20 to 1 and most often from 10 to 2. The used catalyst is partly replaced by fresh catalyst by withdrawal in bottom of the reactor and introduction to the top of the fresh or new catalyst reactor at regular time interval, that is to say for example by puff or almost continuously. For example, fresh catalyst can be introduced every day. The replacement rate of the spent catalyst with fresh catalyst can be, for example, from 0.01 kilogram to 10 kilograms per cubic meter of charge. This withdrawal and replacement are performed using devices for the continuous operation of this hydroconversion step. The unit usually comprises a recirculation pump for maintaining the bubbling bed catalyst by continuously recycling at least a portion of the liquid withdrawn at the top of the reactor and reinjected at the bottom of the reactor. It is also possible to send the spent catalyst withdrawn from the reactor into a regeneration zone in which the carbon and the sulfur contained therein are eliminated and then to return this regenerated catalyst to the hydroconversion stage a). The spent catalyst can also be sent to a rejuvenation zone to partially extract the metals and coke from the feed and deposited on the catalyst. The hydroconverted liquid effluent from the first boiling bed hydroconversion step (step a)) is advantageously subjected to a separation step b) making it possible to produce at least one gasoline fraction, a gas oil fraction and a vacuum gas oil fraction. an unconverted residual fraction. According to the invention, the boiling point of the gasoline fraction (or fraction) is advantageously between 20 and 130 ° C, preferably between 20 and 180 ° C; the boiling point of the fraction (or cut) gas oil is advantageously between 130 and 380 ° C, preferably between 180 and 350 ° C; the boiling point of the gas oil fraction under vacuum is advantageously between 350 and 550 ° C, preferably between 380 and 500 ° C; the boiling point of the unconverted residual fraction is preferably at least 500 ° C or even 550 ° C.
    [0007] This separation step is carried out by any means known to those skilled in the art, in particular by atmospheric fractionation followed by vacuum fractionation. First hydrocracking step According to a variant of the invention, at least part of the gas oil fraction and the vacuum gas oil fraction (VGO according to the English terminology) separated in step b) are treated in a first step of hydrocracking comprising at least one hydrocracking reactor. In the context of the present invention, the term "hydrocracking" includes cracking processes comprising at least one charge conversion step using at least one catalyst in the presence of hydrogen. The hydrocracking may be carried out according to one-step diagrams comprising in the first place a deep hydrorefining which aims to carry out a hydrodenitrogenation and a desulphurization of the feed before the effluent is completely sent to the catalyst of the feed. hydrocracking itself, especially in the case where it comprises a zeolite. It also includes two-step hydrocracking which comprises a first step which aims, as in the "one-step" process, to carry out the hydrorefining of the feed, but also to achieve a conversion of the feedstock. order in general from 30 to 60 percent. In the second step of a two-stage hydrocracking process, generally only the fraction of the unconverted feedstock in the first step is processed. Conventional hydrorefining catalysts generally contain at least one amorphous support and at least one hydro-dehydrogenating element (generally at least one non-noble group VIB and VIII, and most often at least one group VIB element and at least one a non-noble group VIII element).
    [0008] The matrices that can be used in the hydrorefining catalyst alone or as a mixture are, by way of example, alumina, halogenated alumina, silica, silica-alumina, clays (chosen by for example, natural clays such as kaolin or bentonite), magnesia, titanium oxide, boron oxide, zirconia, aluminum phosphates, titanium phosphates, phosphate phosphates and the like. zirconium, coal, aluminates. It is preferred to use matrices containing alumina, in all the forms known to those skilled in the art, and even more preferably aluminas, for example gamma-alumina.
    [0009] The hydrocracking operating conditions are adjusted so as to maximize the production of gasoline while ensuring good operability of the unit. The operating conditions used in the reaction zone (s) of the first hydrocracking stage are generally a mean catalyst bed temperature (WABT) of between 300 and 550 ° C., preferably of between 300 and 500 ° C., more preferably between 350 and 500 ° C, a pressure of between 5 and 35 MPa, preferably between 6 and 25 MPa, a liquid space velocity (charge flow / catalyst volume) generally between 0.1 and 20 h -1, preferably between 0.1 and 10h-1, more preferably between 0.15 and 5h-1. An amount of hydrogen is introduced such that the volume ratio in m3 of hydrogen per m3 of hydrocarbon at the inlet of the hydrocracking step is between 300 and 2000 m3 / m3, most often between 500 and 1800 m3. / m3, preferably between 600 and 1500 m3 / m3. This reaction zone generally comprises at least one reactor comprising at least one fixed-bed hydrocracking catalyst. The fixed bed of hydrocracking catalyst may optionally be preceded by at least one fixed bed of a hydrorefining catalyst (hydrodesulfurization, hydrodenitrogenation, for example). The hydrocracking catalysts used in the hydrocracking processes are generally of the bifunctional type associating an acid function with a hydrogenating function. The acid function can be provided by supports having a large surface area (generally 150 to 800 m 2 g -1) and having a surface acidity, such as halogenated aluminas (chlorinated or fluorinated in particular), and combinations of boron oxides. and aluminum, amorphous silica-aluminas known as amorphous hydrocracking catalysts and zeolites. The hydrogenating function may be provided either by one or more metals of Group VIII of the Periodic Table of Elements, or by a combination of at least one Group VIB metal of the Periodic Table and at least one Group VIII metal. The hydrocracking catalyst may also comprise at least one crystalline acid function such as a zeolite Y, or an amorphous acid function such as a silica-alumina, at least one matrix and a hydrodehydrogenating function.
    [0010] Optionally, it may also comprise at least one element chosen from boron, phosphorus and silicon, at least one element of group VIIA (chlorine, fluorine for example), at least one element of group VIIB (manganese for example), with least one element of the group VB (niobium for example). Hydrotreating step According to another variant of the invention, a hydrotreatment step can be implemented in place of the first hydrocracking step. This variant is particularly well suited to the charges from coal or residues from the hydroconversion stage and having high levels of nitrogen compounds. The hydrotreatment step (HDT) then makes it possible to de-nitrogen these effluents resulting from the H-Oil or H-Coal step (char charge). This avoids sending nitrogen compounds and the ammonia formed on a hydrocracking catalyst and thus to inhibit or even poison it. According to the invention, the hydrotreating step is carried out so that the cracking is limited to less than 40%, preferably less than 30% and more preferably less than 20%. According to the invention, the hydrotreating step is advantageously carried out under a pressure of between 5 and 35 MPa, preferably between 6 and 25 MPa, a temperature of between 320 and 460 ° C., preferably between 340 and 440 ° C, a liquid space velocity (charge flow / catalyst volume) of between 0.1 and 10 h -1, preferably between 0.15 and 4 h -1. The hydrotreatment catalysts used are preferably known catalysts and are generally granular catalysts comprising, on a support, at least one metal or metal compound having a hydrodehydrogenating function. These catalysts are advantageously catalysts comprising at least one Group VIII metal, generally selected from the group consisting of nickel and / or cobalt, and / or at least one Group VIB metal, preferably molybdenum and / or tungsten. . For example, a catalyst comprising from 0.5 to 10% by weight of nickel and preferably from 1 to 5% by weight of nickel (expressed as nickel oxide NiO) and from 1 to 30% by weight of molybdenum, preferably from 5 to 20% by weight of molybdenum (expressed as molybdenum oxide MoO 3) on a mineral support. This support will, for example, be selected from the group formed by alumina, silica, silica-aluminas, magnesia, clays and mixtures of at least two of these minerals. Advantageously, this support contains other doping compounds, in particular oxides chosen from the group formed by boron oxide, zirconia, ceria, titanium oxide, phosphoric anhydride and a mixture of these oxides. Most often an alumina support is used and very often a support of alumina doped with phosphorus and possibly boron. When phosphorus pentoxide P205 is present, its concentration is less than 10% by weight. When B205 boron trioxide is present, its concentration is less than 10% by weight. The alumina used is usually alumina or TI. This catalyst is most often in the form of extrudates. The total content of metal oxides of groups VIB and VIII is often from 5 to 40% by weight and in general from 7 to 30% by weight and the weight ratio expressed as metal oxide between metal (or metals) of Group VIB on metal Group VIII (or metals) is in general from 20 to 1 and most often from 10 to 2.30. Deasphalting step According to the variants, the process according to the invention can carry out a deasphalting step. According to the invention, at least a part of the unconverted residual fraction from step b) can be sent to a deasphalting section in which it is treated in a solvent extraction step in a conditions making it possible to obtain a deasphalted hydrocarbon fraction and residual asphalt. One of the objectives of the deasphalting step is, on the one hand, to maximize the amount of deasphalted oil and, on the other hand, to maintain, or even to minimize, the asphaltene content. This asphaltene content is generally determined in terms of the content of asphaltenes insoluble in heptane, ie measured according to a method described in the AFNOR standard (NF-T 60115) of January 2002. According to the invention, the content asphaltenes of the deasphalted effluent (also called DeAsphalted Oil or DAO according to the English terminology, or deasphalted hydrocarbon fraction or deasphalted oil) is less than 3000 ppm by weight. Preferably, the asphaltene content of the deasphalted effluent is less than 1000 ppm by weight, more preferably less than 500 ppm by weight. Below an asphaltene content of 500 ppm by weight, the method of the AFNOR standard (NF-T 60115) is no longer sufficient to measure this content. The Applicant has developed an analytical method, covering the quantitative analysis of asphaltenes direct distillation products and heavy products from deasphalting residues. This method can be used for asphaltene concentrations of less than 3000 ppm by weight and greater than 50 ppm by weight. The method in question consists in comparing the absorbance at 750 nm of a sample in toluene solution with that of a sample in solution in heptane after filtration. The difference between the two measured values is correlated with the concentration of insoluble asphaltenes in heptane using a calibration equation. This method complements the AFNOR method (NF-T 60115) and the IP143 standard method which are used for higher concentrations. The solvent used in the deasphalting step is advantageously a paraffinic solvent, a petrol cut or condensates containing paraffins.
    [0011] Preferably, the solvent used comprises at least 50% by weight of hydrocarbon compounds having between 3 and 7 carbon atoms, more preferably between 4 and 7 carbon atoms, even more preferably 4 or 5 carbon atoms. Depending on the solvent used, the deasphalted oil yield and the quality of this oil may vary. By way of example, when passing from a solvent containing 3 carbon atoms to a solvent containing 7 carbon atoms, the oil yield increases but, in return, the levels of impurities (asphaltenes, metals, carbon Conradson, sulfur, nitrogen ...) also increase. Moreover, for a given solvent, the choice of operating conditions, in particular the temperature and the quantity of solvent injected, has an impact on the deasphalted oil yield and on the quality of this oil. Those skilled in the art can choose the optimum conditions to obtain an asphaltenes content of less than 500 ppm. The deasphalting step may be carried out by any means known to those skilled in the art. This step is generally carried out in a settling mixer or in an extraction column. Preferably, the deasphalting step is carried out in an extraction column. According to a preferred embodiment, a mixture comprising the hydrocarbon feedstock and a first fraction of a solvent feed is introduced into the extraction column, the volume ratio between the solvent feed fraction and the hydrocarbon feedstock. being called the rate of solvent injected with the charge. This step is intended to mix well the load with the solvent entering the extraction column. In the settling zone at the bottom of the extractor, it is possible to introduce a second fraction of the solvent charge, the volume ratio between the second solvent loading fraction and the hydrocarbon feed being called the solvent content injected at the bottom of the solvent. extractor. The volume of the hydrocarbon feedstock considered in the settling zone is generally that introduced into the extraction column. The sum of the two volume ratios between each of the solvent feed fractions and the hydrocarbon feed is referred to as the overall solvent level. The decantation of the asphalt consists of the countercurrent washing of the asphalt emulsion in the solvent + oil mixture with pure solvent. It is generally favored by an increase in the solvent content (it is in fact to replace the solvent + oil environment with a pure solvent environment) and an increase in temperature. The overall solvent content relative to the treated feedstock is preferably between 2.5 / 1 and 20/1, more preferably between 3/1 and 12/1, more preferably between 4 / 1 and 10/1. This overall solvent content is decomposed into a level of solvent injected with the feedstock at the top of the extractor, preferably between 0.5 and 5/1, preferably between 1/1 and 5/1, and a level of solvent injected extractor bottom preferably between 2/1 and 15/1, more preferably between 3/1 and 10/1. Furthermore, according to a preferred embodiment, a temperature gradient is established between the head and the bottom of the column to create an internal reflux, which improves the separation between the oily medium and the resins. Indeed, the solvent + oil mixture heated at the top of the extractor makes it possible to precipitate a fraction comprising resin which goes down into the extractor. The upward countercurrent of the mixture makes it possible to dissolve at a lower temperature the fractions comprising the resin which are the lightest.
    [0012] In the deasphalting step, the typical temperature at the top of the extractor varies according to the chosen solvent and is generally between 60 and 220 ° C., preferably between 70 and 210 ° C., and the temperature at the bottom of the extractor is preferably between 50 and 190 ° C and more preferably between 60 and 180 ° C.
    [0013] The pressure inside the extractor is generally adjusted so that all the products remain in the liquid state. This pressure is preferably between 4 and 5 MPa. According to the invention, when the deasphalting step is carried out, at least a portion of the hydrocarbon fraction resulting from the deasphalting step is sent to step c) i) of hydrotreatment or step c) ii) hydrocracking, mixed with the gas oil fraction and the vacuum gas oil fraction from step b) and optionally with a direct distillation gas oil fraction and / or a direct distillation gas oil fraction.
    [0014] Second hydroconversion stage The invention may also comprise a second hydroconversion stage. This second hydroconversion stage can be implemented according to the invention in fixed bed or bubbling bed. This second hydroconversion stage is generally carried out on a deasphalted hydrocarbon fraction obtained from the deasphalting stage according to the invention. According to the invention, at least a portion of the deasphalted hydrocarbon fraction obtained from the deasphalting stage is sent to a second hydroconversion stage in the presence of hydrogen, said stage being carried out under hydrocracking conditions. fixed bed or in bubbling bed hydrocracking conditions. The conditions of the second hydroconversion stage of the charge in the presence of hydrogen are usually an absolute pressure of between 5 and 35 MPa, preferably of between 10 and 25 MPa, a temperature of 260 to 600 ° C. and often of 350 to 550 ° C. The hourly space velocity (VVH) and the hydrogen partial pressure are important factors that are chosen according to the characteristics of the product to be treated and the desired conversion. Most often the VVH is in a range from 0.1 h -1 to 10 h -1 and preferably 0.15 h -1 to 5 h -1. According to the invention, the weighted average temperature of the catalytic bed of the second hydroconversion stage is advantageously between 260 and 600 ° C., preferably between 300 and 600 ° C., more preferably between 350 and 550 ° C. The quantity of hydrogen mixed with the feedstock is usually 50 to 5000 normal cubic meters (Nm3) per cubic meter (m3) of liquid feed. Advantageously, the hydrogen is used in a volume ratio with the feed of between 300 and 2000 m3 / m3, preferably between 500 and 1800 m3 / m3, and more preferably between 600 and 1500 m3 / m3. It is possible to use a conventional granular hydroconversion catalyst comprising on an amorphous support at least one or metal compound having a hydrodehydrogenating function. This catalyst may be a catalyst comprising Group VIII metals, for example nickel and / or cobalt, most often in combination with at least one Group VIB metal, for example molybdenum and / or tungsten. For example, a catalyst comprising from 0.5 to 10% by weight of nickel and preferably from 1 to 5% by weight of nickel (expressed as nickel oxide NiO) and from 1 to 30% by weight of molybdenum of preferably from 5 to 20% by weight of molybdenum (expressed as molybdenum oxide MoO 3) on an amorphous mineral support. This support is for example chosen from the group formed by alumina, silica, silica-aluminas, magnesia, clays and mixtures of at least two of these minerals. This support may also contain other compounds and for example oxides chosen from the group formed by boron oxide, zirconia, titanium oxide and phosphoric anhydride. Most often an alumina support is used and very often a support of alumina doped with phosphorus and possibly boron. The P 2 O 5 phosphoric anhydride concentration is usually less than 20% by weight and most often less than about 10% by weight. This P205 concentration is usually at least 0.001% by weight. The concentration of boron trioxide B 2 O 3 is usually from 0 to 10% by weight. The alumina used is usually a gamma or rho alumina. This catalyst is most often in the form of extruded. The total content of metal oxides of groups VI and VIII is often from 5 to 40% by weight and in general from 7 to 30% by weight and the weight ratio expressed as metal oxide between metal (or metals) of Group VI on metal (or metals) of group VIII is generally from 20 to 1 and most often from 10 to 2. The used catalyst is partly replaced by fresh catalyst by withdrawal at the bottom of the reactor and introduction at the top of the fresh catalyst reactor or nine at regular time interval, that is to say for example by puff or almost continuously. For example, fresh catalyst can be introduced every day. The replacement rate of the spent catalyst with fresh catalyst can be, for example, from 0.01 kilogram to 10 kilograms per cubic meter of charge. This withdrawal and replacement are performed using devices for the continuous operation of this hydroconversion step. The unit usually comprises a recirculation pump for maintaining the bubbling bed catalyst by continuously recycling at least a portion of the liquid withdrawn at the top of the reactor and reinjected at the bottom of the reactor. It is also possible to send the spent catalyst withdrawn from the reactor into a regeneration zone in which the carbon and the sulfur contained therein are eliminated and then to return this regenerated catalyst to the second hydroconversion stage. The effluent from the second hydroconversion stage is advantageously subjected to a separation step h) making it possible to produce at least one gasoline fraction, a gas oil fraction, a vacuum gas oil fraction, and an unconverted residual fraction.
    [0015] This separation step h) is carried out by any means known to those skilled in the art, for example a distillation. According to the invention, at least a portion of the gas oil and vacuum gas oil fractions from the separation step h) are sent to the hydrotreatment step c) i) or the hydrocracking step c) ii), in a mixture with the gas oil fraction and the vacuum gas oil fraction from step b) and optionally with a straight-run gas oil fraction and / or a direct distillation gas oil fraction. Second hydrocracking step The method according to the invention may also comprise a second hydrocracking step. This second hydrocracking step is advantageously carried out on at least a portion, preferably all of the gas oil fraction resulting from the fractionation step d). For the sake of homogeneity, even in the case where the process according to the invention does not include the implementation of the first hydrocracking step c) ii), this hydrocracking step of the process will be referred to as the second stage of the process. hydrocracking. The hydrocracking operating conditions are adjusted so as to maximize the production of gasoline while ensuring good operability of the unit. Advantageously, the second hydrocracking step is carried out at a temperature at least 10 ° C. lower than that used during the hydrotreating step c) i) or the first hydrocracking step c. ii), and at a higher liquid space velocity (feed rate / catalyst volume) of at least 30%, preferably at least 45%, more preferably at least 60% than that implemented during the hydrotreatment step c) i) or the first hydrocracking step c) ii). Generally, the average temperature of the catalytic bed (WABT) of the second hydrocracking step is between 300 and 550 ° C, preferably between 250 and 400 ° C. The pressure is generally between a pressure of between 5 and 35 MPa, preferably between 6 and 25 MPa. The liquid space velocity (charge rate / volume of catalyst) is generally between 0.1 and 20 h -1, preferably between 0.1 and 10 h -1, more preferably between 0.15 and 5 h -1.
    [0016] During the second hydrocracking step, a quantity of hydrogen is introduced such that the volume ratio in m3 of hydrogen per m 3 of hydrocarbon input of the hydrocracking step is between 300 and 2000 m 3 / m 3, most often between 500 and 1800 m3 / m3, preferably between 600 and 1500 m3 / m3.
    [0017] This reaction zone generally comprises at least one reactor comprising at least one fixed-bed hydrocracking catalyst. The fixed bed of hydrocracking catalyst may be optionally preceded by at least one fixed bed of a hydrorefining catalyst (hydrodesulfurization, hydrodenitrogenation for example). The hydrocracking catalysts used in the hydrocracking processes are generally of the bifunctional type associating an acid function with a hydrogenating function. The acid function can be provided by supports having a large surface area (generally 150 to 800 m 2 g -1) and having surface acidity, such as halogenated aluminas (chlorinated or fluorinated in particular), combinations of boron oxides and aluminum, amorphous silica-aluminas known as amorphous hydrocracking catalysts and zeolites. The hydrogenating function may be provided either by one or more metals of Group VIII of the Periodic Table of Elements, or by a combination of at least one Group VIB metal of the Periodic Table and at least one Group VIII metal. The hydrocracking catalyst may also comprise at least one crystalline acid function such as a zeolite Y, or an amorphous acid function such as a silica-alumina, at least one matrix and a hydrodehydrogenating function. Optionally, it may also comprise at least one element chosen from boron, phosphorus and silicon, at least one element of group VIIA (chlorine, fluorine for example), at least one element of group VIIB (manganese for example), with least one element of the group VB (niobium for example). First variant of the process according to the invention In a first variant of the process according to the invention called "implementation 1N", the feedstock of the process according to the invention is treated in a first hydroconversion stage (stage a), for example of the H-Oil type and the effluent obtained is separated (step b) into at least one gasoline fraction, a gas oil fraction, a vacuum gas oil fraction and an unconverted residual fraction. The gas oil and vacuum gas oil fractions thus obtained, optionally with a straight-run gas oil fraction and / or a straight run vacuum gas oil fraction (straight run according to the English terminology) are sent either to step c) i) hydrotreatment, either to step c) ii) hydrocracking. According to this first variant of the process of the invention, the effluent resulting from step c) i) of hydrotreatment or from step c) ii) of hydrocracking is fractionated in step d) of fractionation into several fractions including a gasoline fraction, a diesel fraction and an unconverted vacuum gas oil fraction. The fractionation step is carried out by any means known to those skilled in the art, for example a distillation. All or part of the unconverted vacuum gas oil fraction resulting from the fractionation step d) is recycled in the first hydroconversion stage (step a)).
    [0018] At least a portion of the gas oil fraction from the fractionation stage is sent to the second hydrocracking step. The effluent from the second hydrocracking step is returned to fractionation step d). Thus, with reference to FIG. 1, the charge A consisting of a vacuum residue (SR VR) is sent via the pipe 1 to a hydroconversion section 20 (denoted H-OI1Rc in FIG. 1) making it possible to produce after separation (not shown) a fraction (4) gasoline (N), a fraction (5) gas oil (GO), a fraction (6) gas oil under vacuum (VGO) and a residual fraction (3) unconverted (VR). The gas oil (GO) and vacuum gas oil (VGO) fractions are then sent through line 6 to a hydrotreatment or hydrocracking section. This fraction can be sent to the section 30 in admixture with a fraction B of distillate gas oil and / or of gas oil under vacuum distillation (SR GO-VGO). The effluent from the section 30 is then separated in the fractionation zone 40 (denoted FRAC in FIG. 1) into a gasoline fraction (12, N), a gas oil fraction (13, GO) and a vacuum gas oil fraction ( 14, VGO). At least a portion of the VGO is returned via line 9 to the first hydroconversion section 20 in admixture with charge A. This VGO is partly cracked in the hydroconversion section and the unconverted VGO is in turn converted. partially in the hydrocracking or hydrotreating section. At least a portion (13b) of the GO from the fractionation zone (13) is sent to the hydrocracking section 70 (second hydrocracking step). The effluent at the outlet of the section 70 is recycled to the fractionation zone 40 via line 11. Unlike conventional two-stage hydrocracking processes which recycle the bottom of the fractionation unit in the second hydrocracking stage, this configuration makes it possible not to recycle the VGO heavy polyaromatics in the second hydrocracking step, which is in favor of a strong increase in the stability of the hydrocracking catalyst of the hydrocracking section 70 and in the end results in a increased production of gasoline. Thus, compared with the diagram of the prior art shown in FIG. 0 and whose legend is identical to that of FIG. 1, the purges in VGO (14) and in GO (13) are very small and represent at most 1% by weight in favor of an additional co-production in high value added gasoline fraction. Second variant of the process according to the invention A second variant of the process according to the invention called "implementation 2N", zo implements a step of deasphalting. This variant differs from the variant 1N in that at least a portion of the unconverted residual fraction from the separation step b) can be sent to a deasphalting step in which it is treated in an extraction section. using a solvent under conditions making it possible to obtain a deasphalted hydrocarbon fraction and residual asphalt (pitch according to the English terminology). This operation makes it possible to extract a large part of the asphaltenes and to reduce the metal content of the unconverted residual fraction. During this deasphalting step, the latter elements are concentrated in an effluent called asphalt or residual asphalt. The deasphalted effluent, often referred to as deasphalted oil (also known as DAO), has a reduced content of asphaltenes and metals. According to this variant of the process called "2N implementation", the deasphalted hydrocarbon fraction resulting from the deasphalting step is sent to step c) i) of hydrotreatment or step c) ii) of hydrocracking, in mixing with the gas oil fraction and the vacuum gas oil fraction from step b) and optionally with a straight-run gas oil fraction and / or a straight-run gas-oil fraction. The hydrotreatment or hydrocracking effluent is then fractionated in the fractionation zone in several fractions including a gasoline fraction, a gas oil fraction and an unconverted vacuum gas oil fraction. At least a portion of the vacuum gas oil fraction from fractionation step d) is recycled to the deasphalting stage inlet and / or to the first hydroconversion stage. At least a portion of the gas oil fraction from the fractionation stage is sent to the second hydrocracking step. The effluent from the second hydrocracking step is returned to fractionation step d). Thus, referring to FIG. 2, the vacuum charge A (SR VR) is sent via line 1 to a hydroconversion section 20 (denoted H-OilRc in FIG. 2) making it possible to produce after separation ( not shown) a gasoline fraction (4), a gas oil fraction (5), a vacuum gas oil fraction (VGO) and a non-converted residual fraction (3) (VR). The gas oil (GO) and vacuum gas oil (VGO) fractions are sent via line 6 to the hydrotreatment or hydrocracking section. The unconverted residual fraction (VR) is sent via line 3 to a deasphalting unit 50 (SDA) for extracting a deasphalted oil (DAO) and a residual asphalt (Pitch) through line 16. The deasphalted oil fraction ( DAO) is then sent through line 15 to a hydrotreatment or hydrocracking section. The effluent from the section 30 is then separated in the fractionation zone 40 into a gasoline fraction (12, N), a gas oil fraction (13, GO) and a vacuum gas oil fraction (14, VGO). At least a portion of the vacuum gas oil fraction (14, VGO) is returned via lines 9 and 2 to the deasphalting section 50 and / or to the first hydroconversion section through lines 9 and 10. the vacuum gas oil fraction (14, VGO) in the deasphalting unit makes it possible to send an additional quantity of deasphalted oil (DAO) into the first hydrocracking step (section 30) and to induce an additional production of petrol. The recycling of the vacuum gas oil fraction (14, VGO) in the first hydroconversion section 20 allows the additional cracking of the gas oil and gasoline vacuum gas oil fraction without any impact on the operation of the unit of this section.
    [0019] At least a portion (13b) of the gas oil fraction (13) from the fractionation zone is sent to the hydrocracking section 70 (second hydrocracking step). The effluent leaving the section 70 is recycled to the fractionation zone 40 via the pipe 11. In this variant, the hydrotreatment or hydrocracking section 30 and then the fractionation zone 40 are fed both with the fractions gas oil and vacuum gas oil from the first hydroconversion stage, and the deasphalted oil (DAO) from the deasphalting step and optionally with a direct distillation gas oil fraction and / or a direct distillation gas oil fraction. Gasoline production is significantly increased. Third variant of the process according to the invention The third variant of the process according to the invention called "3N implementation" differs from the second variant in that the deasphalted hydrocarbon fraction obtained from the deasphalting stage is sent to a second hydroconversion stage in the presence of hydrogen: this step can be carried out under fixed-bed hydrocracking conditions or under bubbling bed hydrocracking conditions so as to preferably produce after a separation step h) a gasoline fraction, a gas oil fraction, a vacuum gas oil fraction, and a non-converted residual fraction In this variant, the gas oil and vacuum gas oil fractions from the separation step h) are sent to step c) i) hydrotreatment step or hydrocracking step c) ii), in a mixture with the gas oil fraction and the vacuum gas oil fraction resulting from step b) and optionally with a fraction straight-run diesel fuel and / or a straight-run vacuum gas oil fraction.
    [0020] According to this variant of the process of the invention, the hydrotreatment or hydrocracking effluent is fractionated in the fractionation zone (step d)) in several fractions including a gasoline fraction, a gas oil fraction and a non-vacuum gas oil fraction. converted. According to this variant of the invention called "implementation 3N", at least a portion of the vacuum gas oil fraction from the fractionation step d) is recycled at the inlet of the deasphalting step, and / or at the inlet of the first hydroconversion stage. At least a portion of the gas oil fraction from the fractionation stage is sent to the second hydrocracking step. The effluent from the second hydrocracking step is returned to fractionation step d). Thus, referring to FIG. 3, the vacuum residue charge A (SR VR) is sent via line 1 to a hydroconversion section 20 (denoted H-OilRc in FIG. 3) making it possible to produce after separation ( not shown) a gasoline fraction (4), a gas oil fraction (5), a vacuum gas oil fraction (VGO) and a non-converted residual fraction (3) (VR). The gas oil fractions (5, GO) and vacuum gas oil (6, VGO) are sent through line 6 to the hydrotreatment or hydrocracking section. The unconverted residual fraction (VR) is sent via line 3 to a deasphalting unit 50 (SDA) for extracting a deasphalted oil (DAO) and a residual asphalt (Pitch) through line 16. The deasphalted oil fraction ( DAO) is then sent via line 15 to a hydroconversion section 60 (denoted H-OilDc in FIG. 3) making it possible to produce a gasoline fraction (18), a diesel fuel fraction (17) and a gasoline fraction (18). fraction (7) vacuum gas oil (VGO) and a residual fraction (19) unconverted (VR). The gas oil fractions (17, GO) and vacuum gas oil (7, VGO) from section 60 are then sent via line 6 to the hydrotreatment or hydrocracking section. The effluent from the section 30 is then separated in the fractionation zone 40 into a gasoline fraction (12, N), a gas oil fraction (13, GO) and a vacuum gas oil fraction (14, VGO). At least a portion of the vacuum gas oil fraction (14, VGO) is returned via lines 9 and 2 to the deasphalting section 50 and / or to the first hydroconversion section through lines 9 and 10. the vacuum gas oil fraction (14, VGO) in the deasphalting unit makes it possible to send an additional quantity of deasphalted oil (DAO) into the first hydrotreatment or hydrocracking step (section 30) and to induce additional production of gasoline. The recycling of the vacuum gas oil fraction (14, VGO) in the first hydroconversion section 20 allows the cracking of the gas oil and gasoline vacuum gas oil fraction without any impact on the operation of the unit of this section.
    [0021] At least a portion (13b) of the gas oil fraction (13) from the fractionation zone is sent to the hydrocracking section 70 (second hydrocracking step). The effluent leaving the section 70 is recycled to the fractionation zone 40 via line 11.
    [0022] EXAMPLES The filler used in these examples has the composition detailed in Table 1. It is a vacuum residue of the "Arabian Heavy" type, that is to say a vacuum residue obtained by distillation of a crude oil from the Arabian Peninsula.
    [0023] Table 1: Composition of the load used ("Arabian Heavy" vacuum residue) Property Unit Value Density - 1,040 Viscosity at 100 ° C cSt 5200 Conradson carbon% weight 23,5 Asphaltenes in C7% weight 13,8 Nickel ppm 52 Vanadium ppm 140 Nitrogen ppm 5300 Sulfur% Weight 5.4 Cut 565 ° C * * Weight 16.45 * Cup containing products with a boiling point below 565 ° C.
    [0024] This charge is implemented in the different process variants illustrated by the implementation schemes 0, 1N, 2N, 3N (represented respectively in FIGS. 0, 1, 2 and 3) without the addition of distillation gas oil and / or distillative vacuum gas oil (SR GO-VGO) at the inlet of the hydrocracking step (HCK) or hydrotreating step (HDT). Furthermore, with regard to the 2N and 3N implementation schemes, the VGO recycle from the fractionation is only sent to the deasphalting unit (SDA), while it is sent to the first hydroconversion unit H-OilRc in the case of scheme 1N.
    [0025] The operating conditions of the conversion units H-OilRc, H-OilDc, first unit and second hydroconversion unit, first unit and second unit HCK (hydrocracking units) in a first variant using two hydrocracking units as well as of the solvent deasphalting unit (SDA) are summarized in Table 2. Table 2a summarizes the operating conditions of the units in a second variant using conversion sections H-OilRc, H-OilDc, first unit and second hydroconversion unit, a hydrotreating unit HDT (replacing the first hydrocracking unit), a hydrocracking unit and Io a solvent deasphalting unit (SDA). H-Oil hydroconversion units are operated with bubbling bed reactors and hydrocracking units with fixed bed reactors. The deasphalting unit is operated with an extraction column. Table 2: Operating Conditions of the Units Parameter H-OilRc H-Oiloc HCK HCK SDA (1st (2nd step) step) VVH Liquid h-1 0.25 0.3 0.5 1.2 - MPa Pressure 18 17 18 18 4.5 WABT SOR * ° C 420 445 385 370 - Extractor temperature 120 at the extractor head 90 at the bottom of the extractor H2 / Charge m3 / m3 400 300 1000 1000 - Solvent / charge Extractor inlet Bottom extractor m3 / m3 - - - - 2/1 m3 / m3 4/1 Catalyst HOC 458TM HRK 1448TM - HTS 458TM HYK 732TM HYK 732TM - Composition Catalysts N1Mo / A1203 NiMo / A1203 N1Mo / A1203 NiMo / zeolite NiMo / zeolite YY * Weighted average temperature in the Table 2bis: Operating conditions of the units Parameter H-OilRc H-Oiloc HDT HCK SDA VVH Liquid h-1 0.25 0.3 0.7 0 , 8 - MPa pressure 18 17 18 18 4.5 WABT SOR * ° C 420 445 390 375 - Extractor temperature 120 at the extractor head 90 at the bottom of the extractor H2 / Charge m3 / m3 400 300 1000 1000 - Solvent / ch extractor inlet Extracting bottom m3 / m3 - - - - 2/1 m3 / m3 4/1 Catalyst HOC 458TM HTS 458TM HRK 1448TM HYK 732TM - Composition NiMo / A1203 NiMo / A1203 NiMo / A1203 NiMo / zeolite Y * Weighted average temperature The catalyst catalysts used are catalysts marketed by the company Axens. The solvent used in the SDA unit is a mixture of butanes comprising 60% nC4 and 40% iC4. The yields of products obtained with the operating conditions of Table 2 are shown in Table 3 as the percentage by weight of each product obtained relative to the initial weight of vacuum residue feedstock (SR VR) introduced into the process. Table 3: Product yields according to the process scheme used% wt. SR VR * Figure 0 Variant 1N Variant 2N Variant 3N (Art (HCK 1 er (HCK 1 st (HCK 1 Anterior) step) step) step) (Invention) (invention) (invention) LN 8 21 22 23 HN 9 42 45 49 GO 47 <1 <1 <1 VGO 5 1 7 2 RV + pitch (Pitch) 22 22 10 11 Total liquid 91 87 84 86 * LN: Light Naphtha (light Naphtha), HN: Heavy Naphtha (Heavy Naphtha), GO: Gas oil, VGO: Vacuum gas oil (Vacuum Gasoil), VR: Vacuum residue (Vacuum Residu), SR Direct distillation (Straight Run). According to the Anglo-Saxon terminology It appears that the 1N, 2N and 3N variants with a hydrocracking (HCK 1st step) in step c) according to the invention promote the formation of light (LN) and heavy (HN) Naptha, and a decrease in the overall liquid yield due to further conversion.
    [0026] This reduction in the liquid yield is however very limited and between 4% and 7% compared to the scheme according to the prior art (scheme 0).
    [0027] At the same time, there is a significant increase in Naphtha yield from 8% (Scheme 0) to over 20% (1N, 2N, 3N Schemes) for Naphtha and 9% at 40%. and 50% for heavy Naptha.
    [0028] The overall yield of Naphtha can thus reach 72% with the 3N scheme with a negligible production of GO and VGO (<3%), the other main products being the pitch and the vacuum residue (Brai from the SDA unit and VR effluent from the H-OilDC unit) that represent about 10% yield points. Figure 1N shows higher yields of VR + pitch than 2N and 3N. Table 3a describes the results obtained when the first hydrocracking of step c) i) is replaced by a hydrotreating with the operating conditions indicated in Table 2bis. Table 3a: Product yields according to the process scheme used% wt. SR VR * Figure 0 Variant 3N (Art (HDT) Anterior) (invention) LN 8 24 HN 9 51 GO 47 <1 VGO 5 1 VR + pitch (Pitch) 22 11 Total liquid 91 87 15 It would appear that variant 3N put using a hydrotreatment step (HDT) instead of the first hydrocracking stage, leads to a significant formation of light Naphtha (LN) and heavy (HN) and a significant decrease in the liquid yield compared to the art prior. The results obtained are of the same order of magnitude as for the 1N, 2N and 3N variants used with the first hydrocracking step (Table 3), or even slightly higher. The removal of contaminants from the hydrotreating section and therefore their absence in the second hydrocracking stage could explain these results. Table 4 shows the properties of the different products obtained by means of the different process schemes.
    [0029] Table 4: Properties of Products Derived from Hydrocracking LN HN Oct Points 30-80 80-150 Cut Density - 0.685 0.755 Sulfur ppm <1 <1 P / N / A *% Weight 63/36/1 31/66 / 3 Cétane - - - * Paraffins / Naphtènes / Aromatiques The naphthas resulting from the hydrocracking stage can be recovered as such, for example in catalytic reforming units in order to produce gasoline. Vacuum residues (VR from H-OilRc unit, VR from H-OilDc unit and asphalt from deasphalting) are mainly recovered as heavy fuel oil after viscosity adjustment by mixing with distillates available on site.
    权利要求:
    Claims (13)
    [0001]
    REVENDICATIONS1. A process for the deep conversion of a heavy hydrocarbon feedstock comprising the following steps: a) a first hydroconversion stage in a bubbling bed of the feedstock, in the presence of hydrogen, comprising at least one triphasic reactor containing at least one catalyst of bubbling bed hydroconversion, b) a step of separating at least a portion of the hydroconverted liquid effluent from step a) into a gasoline fraction, a gas oil fraction, a vacuum gas fraction, and a non-residual fraction. converted, c) i) a step of hydrotreating at least a portion of the gas oil fraction and the vacuum gas oil fraction from step b) in a reactor comprising at least one fixed bed hydrotreatment catalyst ii) a first hydrocracking step of at least a portion of the gas oil fraction and of the vacuum gas oil fraction resulting from step b) in a reactor comprising at least one fixed bed hydrocracking catalyst, d) a step of fractionation of at least a portion of the effluent from step c) i) or step c) ii) into a gasoline fraction, a gas oil fraction and an unconverted vacuum gas oil fraction, e ) a step of recycling at least a portion of the unconverted vacuum gas oil fraction from fractionation stage d) in said first hydroconversion stage a), f) a second stage of hydrocracking of at least one part of the diesel fraction from fractionation step d), g) a step of recycling all or part of the effluent from step f) in fractionation step d).
    [0002]
    2) Process according to claim 1 wherein at least a portion of the unconverted residual fraction from step b) is sent to a deasphalting section in which it is treated in an extraction step with the aid of a solvent under conditions to obtain a deasphalted hydrocarbon cut and residual asphalt.
    [0003]
    3) Process according to claim 2 wherein at least a portion of the deasphalted hydrocarbon fraction from the deasphalting step is sent in step c) i) hydrotreatment or step c) ii) hydrocracking in a mixture with the gas oil fraction and the vacuum gas oil fraction from step b) and optionally with a straight-run gas oil fraction and / or a direct distillation gas oil fraction.
    [0004]
    4) The method of claim 2 wherein at least a portion of the deasphalted hydrocarbon fraction from the deasphalting step is sent in a second hydroconversion stage in the presence of hydrogen, said step being carried out in fixed bed or in bubbling bed.
    [0005]
    5) Process according to claim 4 wherein the effluent from the second hydroconversion stage is subjected to a separation step h) making it possible to produce at least one gasoline fraction, a gas oil fraction, a vacuum gas oil fraction, and an unconverted residual fraction.
    [0006]
    6. A process according to claim 5 wherein at least a portion of the gas oil and gas oil fractions from vacuum from step h) are sent to step c) i) hydrotreatment or step c) ii) hydrocracking, mixed with the gas oil fraction and the vacuum gas oil fraction from step b) and optionally with a direct distillation gas oil fraction and / or a direct distillation gas oil fraction.
    [0007]
    7) Method according to one of claims 2 to 6 wherein at least a portion of the vacuum gas oil fraction from the fractionation step d) is recycled to the input of the deasphalting step, and / or input of the first hydroconversion stage.
    [0008]
    8) Method according to one of the preceding claims wherein the hydroconversion step a) is carried out under an absolute pressure of between 5 and 35 MPa, at a temperature of 260 to 600 ° C and a space velocity ranging from 0.05 h-1 to 10h-1.
    [0009]
    9) Method according to one of the preceding claims wherein the operating conditions used in the hydrotreating step c) i) are a pressure between 5 and 35 MPa, a temperature between 320 and 460 ° C, a space velocity liquid between 0.1 and 10h-1.
    [0010]
    10) Method according to one of the preceding claims wherein the operating conditions used in the first step of hydrocracking c) ii) are an average temperature of the catalyst bed of between 300 and 550 ° C, a pressure of between 5 and 35 MPa, a liquid space velocity of between 0.1 and 20h-1.
    [0011]
    11) Method according to one of the preceding claims wherein the second hydrocracking step is carried out at a temperature at least 10 ° c lower than that implemented in step c) i) d) hydrotreatment or the first hydrocracking step c) i), and at a liquid space velocity (feed rate / catalyst volume) higher by at least 30%, preferably by at least 45%, more preferred at least 60% than that used during the hydrotreating step c) i) or the first hydrocracking step c) i). 25
    [0012]
    12) Method according to one of claims 2 to 11 wherein, in the deasphalting step, the typical temperature at the extractor head is between 60 to 220 ° C and the bottom temperature of the extractor is between 50 and 190 ° C.
    [0013]
    13) Method according to one of the preceding claims wherein the filler is selected from the heavy hydrocarbon feeds of the atmospheric or vacuum residues type obtained for example by direct distillation of petroleum fraction or by vacuum distillation of crude oil, the charges of type distillates such as vacuum gas oils or deasphalted oils, asphalts from solvent deasphalting petroleum residues, coal suspended in a hydrocarbon fraction such as for example gas oil obtained by vacuum distillation of crude oil or distillate from the liquefaction of coal, alone or as a mixture.
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    US11041128B2|2018-08-07|2021-06-22|Chevron U.S.A. Inc.|Catalytic remedy for advanced UCO bleed reduction in recycle hydrocracking operations|
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    申请号 | 申请日 | 专利标题
    FR1462713A|FR3030567B1|2014-12-18|2014-12-18|PROCESS FOR DEEP CONVERSION OF RESIDUES MAXIMIZING PERFORMANCE IN GASOLINE|FR1462713A| FR3030567B1|2014-12-18|2014-12-18|PROCESS FOR DEEP CONVERSION OF RESIDUES MAXIMIZING PERFORMANCE IN GASOLINE|
    CA2915282A| CA2915282A1|2014-12-18|2015-12-14|Deep conversion process for residue maximising the efficiency of gasoline|
    CN201510949670.2A| CN105713664B|2014-12-18|2015-12-18|Conversion residue is improved, the maximized method of gasoline yield is made|
    US14/974,968| US9745527B2|2014-12-18|2015-12-18|Process for the intense conversion of residues, maximizing the gasoline yield|
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